Title of article :
A new intramolecular migration of the imino group of O-arylketoximes to the aryl group under the Beckmann condition
Author/Authors :
Kikugawa، نويسنده , , Yasuo and Tsuji، نويسنده , , Chiho and Miyazawa، نويسنده , , Etsuko and Sakamoto، نويسنده , , Takeshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
ZrCl4-mediated decomposition of O-arylketoximes in benzene leads to regioselective intramolecular migration of the imino group from the oxygen to the ortho position of the aryl group via electron-deficient nitrogen intermediates.
Keywords :
ZrCl4 , Beckmann condition , O-aryloxime , electron-deficient nitrogen
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters