Author/Authors :
Blake، نويسنده , , Alexander J and Friend، نويسنده , , Christopher L and Outram، نويسنده , , Robert J and Simpkins، نويسنده , , Nigel S and Whitehead، نويسنده , , Andrew J، نويسنده ,
Abstract :
The reaction of silylketenes with thiophenol, mediated by cinchona alkaloid catalysts, proceeds to give α-silylthioester products in good chemical yield and with enantiomeric excess values in the range 79–93%. The absolute configuration of one of the thioester products was determined by X-ray diffraction.
