Title of article :
Enantioselective allylation of the α-sulfonyl radical controlled by coordination of a chiral Lewis acid to an enantiotopic sulfonyl oxygen
Author/Authors :
Watanabe، نويسنده , , Yoshihiko and Mase، نويسنده , , Nobuyuki and Furue، نويسنده , , Ryuji and Toru، نويسنده , , Takeshi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Selective coordination of a chiral Lewis acid to an enantiotopic sulfonyl oxygen enabled enantioselective allylation of the α-sulfonyl radical. The addition–allylation products were obtained in low to good stereoselectivities (up to 84% ee).
Keywords :
?-sulfonyl radical , allyltin , enantioselective allylation , vinyl sulfone
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters