Title of article
Vinyl hydrogen more reactive than benzyl hydrogen toward base in significantly twisted styrenes
Author/Authors
Mori، نويسنده , , Hajime and Matsuo، نويسنده , , Takafumi and Yoshioka، نويسنده , , Yasunori and Katsumura، نويسنده , , Shigeo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
3093
To page
3095
Abstract
The novel example of vinyl hydrogen more reactive than benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O quenching. The characteristic nature of the vinyl hydrogen, which is activated by σ–π* orbital interaction, was apparently demonstrated.
Keywords
vinyl hydrogens , carbanions , twisted 1 , 3-dienes
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644504
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