Title of article
An S-oxide of 6-tert-butyl-6-phenylpentathiane. Structure in the crystalline state and in solution and thermal decomposition
Author/Authors
Ishii، نويسنده , , Akihiko and Oshida، نويسنده , , Hideaki and Nakayama، نويسنده , , Juzo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
3117
To page
3119
Abstract
Oxidation of 6-tert-butyl-6-phenylpentathiane with trifluoroperacetic acid gave the pentathiane 3-oxide mainly as the monooxide. The 3-oxide takes a twist conformation both in the crystalline state and in solution. Thermal decomposition of the 3-oxide in the presence of 2,3-dimethyl-1,3-butadiene yielded both S2O- and S2-transferred products.
Keywords
Thermolysis , structure , Oxidation , pentathiane 3-oxide , pentathiane
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644523
Link To Document