Title of article
Nickel-catalyzed preparation of stereodefined allylic alcohols using silicon-tethered ynals
Author/Authors
Lozanov، نويسنده , , Mario and Montgomery، نويسنده , , John، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
3259
To page
3261
Abstract
The nickel-catalyzed cyclization of silicon-tethered ynals is reported. The silicon heterocycles obtained may be converted into allylic alcohols that possess a stereodefined alkene unit via a cleavage process that involves stereospecific protodesilylation of the vinyl silane functionality.
Keywords
silicon heterocycles , nickel , alkenes
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644624
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