Zinc(II) promoted conversion of aryltriazenes to aryl iodides and aryl nitriles
Author/Authors :
Patrick ، نويسنده , , Timothy B and Juehne، نويسنده , , Thomas and Reeb، نويسنده , , Elmer and Hennessy، نويسنده , , Daniel، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
2
From page :
3553
To page :
3554
Abstract :
Aryltriazenes react with zinc perchlorate/zinc cyanide to produces arylnitriles and react with zinc iodide to produce aryliodides. The reaction mechanism involves aryl radicals that have been trapped by addition to propenenitriles in a good preparative Meerwein arylation process.
