Title of article
Regioselective cleavage of the cyclic ethereal bond of 7-oxabicyclo[2.2.1]heptane derivatives mediated by samarium(II) iodide
Author/Authors
Yoshida، نويسنده , , Akihiro and Takayama، نويسنده , , Hiroaki، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
3603
To page
3606
Abstract
It was established that exclusively high regioselective CO bond cleavage of 7-oxabicyclo[2.2.1]heptane skeletons, which are unique Diels–Alder products of furans, under mild conditions using samarium(II) iodide and samarium powder yields cyclohexanol derivatives or aromatic compounds.
Keywords
Diels–Alder reactions , Furans , Sulfur heterocycles , samarium and compounds , Cleavage reactions , regiocontrol
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644886
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