• Title of article

    Regioselective cleavage of the cyclic ethereal bond of 7-oxabicyclo[2.2.1]heptane derivatives mediated by samarium(II) iodide

  • Author/Authors

    Yoshida، نويسنده , , Akihiro and Takayama، نويسنده , , Hiroaki، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    3603
  • To page
    3606
  • Abstract
    It was established that exclusively high regioselective CO bond cleavage of 7-oxabicyclo[2.2.1]heptane skeletons, which are unique Diels–Alder products of furans, under mild conditions using samarium(II) iodide and samarium powder yields cyclohexanol derivatives or aromatic compounds.
  • Keywords
    Diels–Alder reactions , Furans , Sulfur heterocycles , samarium and compounds , Cleavage reactions , regiocontrol
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1644886