Author/Authors :
Tsunashima، نويسنده , , Keiji and Ide، نويسنده , , Mitsuaki and Kadoi، نويسنده , , Hiroshi and Hirayama، نويسنده , , Aya and Nakata، نويسنده , , Masaya، نويسنده ,
Abstract :
The C15–C27 portion of venturicidin X was prepared using substitution reactions of alkyl trifluoromethanesulfonates with a vinylmetal compound followed by homogeneous hydrogenation. Together with our previous synthesis of the C1–C14 portion of venturicidin X, a formal total synthesis of venturicidin X was completed.
Keywords :
venturicidins , two-stage coupling process , Substitution , Hydrogenation
