Title of article
Dynamic kinetic resolution of hemiaminals with axially chiral twisted amides
Author/Authors
Yamada، نويسنده , , Shinji and Noguchi، نويسنده , , Emiko، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
3621
To page
3624
Abstract
Dynamic kinetic resolution of N-acylhemiaminals was performed by enantioselective acylation of the hydroxy groups with chiral twisted amides. The stereoselectivity was reversed in the presence of 4-DMAP. The absolute configuration of the products was determined based on the sign of CD Cotton effects.
Keywords
dynamic kinetic resolution , Hemiaminal , twisted amide , acylation
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1644895
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