Author/Authors :
Kawaguchi، نويسنده , , Masaru and Ikeda، نويسنده , , Atsushi and Shinkai، نويسنده , , Seiji، نويسنده ,
Abstract :
A novel capsular molecule in which three porphyrin-based building blocks are capped by two ionophoric calixarene molecules has been synthesized for the first time. The Zn(II) complex showed a high encapsulation ability for C3-symmetrical guest molecules. In addition, the binding properties were allosterically controlled by added Na+ or CH3OH.