Title of article
Vinylcyclopropyl TMM diyls: access to eight-membered rings
Author/Authors
Raymond F. Mikesell، نويسنده , , Peter Jay and Little، نويسنده , , R.Daniel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
4095
To page
4097
Abstract
Vinylcyclopropyl substituted diazenes (e.g. 1 and 15) rearrange when heated. The chemistry takes place via the formation of a trimethylenemethane (TMM) diyl and provides access to eight-membered rings. When the cyclopropane is fused to a five-membered ring (e.g. 15) rearrangement leads to a structure resembling the taxotere framework.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1645268
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