• Title of article

    Vinylcyclopropyl TMM diyls: access to eight-membered rings

  • Author/Authors

    Raymond F. Mikesell، نويسنده , , Peter Jay and Little، نويسنده , , R.Daniel، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    4095
  • To page
    4097
  • Abstract
    Vinylcyclopropyl substituted diazenes (e.g. 1 and 15) rearrange when heated. The chemistry takes place via the formation of a trimethylenemethane (TMM) diyl and provides access to eight-membered rings. When the cyclopropane is fused to a five-membered ring (e.g. 15) rearrangement leads to a structure resembling the taxotere framework.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1645268