Title of article :
Highly diastereoselective photoaddition of methanol to limonene
Author/Authors :
Kim، نويسنده , , Dong Suk and Shim، نويسنده , , Sang Chul and Wada، نويسنده , , Takehiko and Inoue، نويسنده , , Yoshihisa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Extremely high diastereomeric excess was achieved from the photosensitized polar addition of methanol to (R)-(+)-limonene 1. Diastereomeric excess was varied from 28.1 to 96.3% depending on the solvent polarity, reaction temperature, and structure of sensitizer.
Keywords :
Temperature effect , asymmetric photochemical reaction , Diastereomeric excess , limonene , Photosensitizer , Solvent polarity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
