Author/Authors :
Legros، نويسنده , , Julien and Crousse، نويسنده , , Beno??t and Bourdon، نويسنده , , Jack and Bonnet-Delpon، نويسنده , , Danièle and Bégué، نويسنده , , Jean-Pierre، نويسنده ,
Abstract :
The fluoroalkylketone 2 is an efficient catalyst in the epoxidation reaction using Oxone® as oxidant. In hexafluoro-2-isopropanol (HFIP), the ketone can be used in a catalytic amount (1 or 5 mol%) with only 1.5 equiv. of Oxone®. The reaction gave good yields of epoxides for a number of olefin substrates, included low reactive ones.
