Title of article
Chemoselective hydroperoxidation of alkenylarenes within thionin-supported zeolite Na-Y
Author/Authors
Stratakis، نويسنده , , Manolis and Rabalakos، نويسنده , , Constantinos، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
4545
To page
4547
Abstract
Photooxidation of several 1-aryl-2-methylpropenes within the thionin-supported zeolite Na-Y affords the ene type allylic hydroperoxides in a highly chemoselective manner. This is in contrast to their photooxygenation reaction in solution, where the ene pathway is less favorable compared to the [4+2] or [2+2] pathways. Cation-π interactions are likely to be responsible for this selectivity.
Keywords
zeolite Na-Y , ene reactions , singlet oxygen , Zwitterions
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1645631
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