Title of article
Novel chiral phosphine–oxazinane ligands in palladium-catalyzed asymmetric allylic alkylation
Author/Authors
Mino، نويسنده , , Takashi and Hata، نويسنده , , Sosuke and Ohtaka، نويسنده , , Kouji and Sakamoto، نويسنده , , Masami and Fujita، نويسنده , , Tsutomu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
4837
To page
4839
Abstract
Palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate (8a) with a dimethyl malonate–BSA–LiOAc system has been successfully carried out in the presence of novel chiral phosphine–oxazinane ligands such as 5b in good yields with good enantioselectivities (up to 95% ee).
Keywords
oxazinane , asymmetric synthesis , phosphine , PALLADIUM
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1645862
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