Author/Authors :
Gallos، نويسنده , , John K and Damianou، نويسنده , , Katerina C and Dellios، نويسنده , , Constantinos C، نويسنده ,
Abstract :
A new total synthesis of enantiomerically pure pentenomycin has been achieved by the intramolecular nitrone cycloaddition of the proper γ-unsaturated aldehyde, easily accessible from l-arabinose, followed by reductive NO bond cleavage and further oxidative deamination of the resulting aminocyclopentitol.
