Author/Authors :
Chrisman، نويسنده , , Will and Camara، نويسنده , , Jason N and Marcellini، نويسنده , , Kim and Singaram، نويسنده , , Bakthan and Goralski، نويسنده , , Christian T and Hasha، نويسنده , , Dennis L and Rudolf، نويسنده , , Philip R and Nicholson، نويسنده , , Lawrence W and Borodychuk، نويسنده , , Karen K، نويسنده ,
Abstract :
A series of chiral β-amino alcohols was prepared by the reaction of secondary amines with a 1:1 mixture of cis- and trans-limonene oxide in the presence of water as a catalyst. The β-amino alcohol obtained was derived from the trans-limonene oxide, and the unreacted cis-limonene oxide was recovered from the reaction mixture. The β-amino alcohols are useful chiral auxiliaries for the addition of diethylzinc to benzaldehyde.
