Author/Authors :
Han، نويسنده , , Xiaojun and Hartmann، نويسنده , , Gregory A and Brazzale، نويسنده , , Antony and Gaston، نويسنده , , Rick D، نويسنده ,
Abstract :
Synthesis of a water-soluble recyclable organostannatrane has been accomplished via a straightforward three-step synthesis. The organostannatrane exhibits excellent water-solubility (0.33 M) and can be recovered from aqueous solutions via removal of water in vacuo. The compound can be readily converted by standard transformations into reagents suitable for Stille cross-coupling reactions. The reagent can also be transformed into a reactive, water-soluble organotin hydride.
