Title of article :
Regioselective monohalogenation of 3,3-disubstituted bornane-2-thiones via thione–dihalogen complexes
Author/Authors :
Shimada، نويسنده , , Kazuaki and Nanae، نويسنده , , Takashi and Aoyagi، نويسنده , , Shigenobu and Takikawa، نويسنده , , Yuji and Kabuto، نويسنده , , Chizuko، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
Reaction of 3,3-disubstituted bornane-2-thiones with Br2, ICl, or Cl2 afforded the corresponding 10-bromobornane-2-thiones, 10-iodobornane-2-thiones, or the products originated from skeletal rearrangement of 10-chlorobornane-2-thiones, respectively.
Keywords :
Halogenation , bornane-2-thione , 10-halobornane-2-thione , dihalosulfurane , thione–I2 CT complex
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
