• Title of article

    Heterogeneous acid-catalyzed (2,5) oxonium-ene reaction for eight-membered ring formation

  • Author/Authors

    Ohmura، نويسنده , , Hirofumi and Mikami، نويسنده , , Koichi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2001
  • Pages
    5
  • From page
    6859
  • To page
    6863
  • Abstract
    The (2,5) ene cyclization of cyclic allylic lactol ether 1 as a substrate gave aldehyde 3 presumably via the intermediate 2. Furthermore, ring cleavage at the CO bond of the oxolane moiety in the aldehyde 3 under reductive conditions afforded the eight-membered ring regioselectively.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2001
  • Journal title
    Tetrahedron Letters
  • Record number

    1647316