Title of article
4-(Trialkylsilyl)oxybut-2-ynals as dienophiles in the Diels–Alder synthesis of α-(hydroxymethyl)benzaldehydes
Author/Authors
Morrison، نويسنده , , Christopher F and Burnell، نويسنده , , D.Jean، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
7367
To page
7369
Abstract
The α-(hydroxymethyl)benzaldehyde derivative 2 has been synthesized by heating ynal 3 with diene 5, which produced the α-(silyloxymethyl)benzaldehyde 6 by a Diels–Alder/retro-Diels–Alder process, followed by methylation, thioacetalization, and removal of the silyl protecting group. Decarbonylation of α-(silyloxymethyl)benzaldehydes 6 and 10 takes place readily in the presence of zinc(II) chloride or para-toluenesulfonic acid.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647655
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