Title of article
Organophosphorus compounds. Part 163: Reactivity of phosphaalkynes towards in situ-generated titanium imido complexes
Author/Authors
Asmus، نويسنده , , Sven M.F and Regitz، نويسنده , , Manfred، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
7543
To page
7545
Abstract
Treatment of kinetically stabilized phosphaalkynes 5 in toluene with primary amines 4 in the presence of equimolar amounts of cyclopentadienyltitaniumtrichloride (2) leads to azaphosphatitanacyclobutane species 6. The formation of compounds 6 enables a first insight into the mechanism of the reaction of titanium imides with phosphaalkynes, presented in several recent papers.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647884
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