Title of article
Mild and selective reductions of aryl halides catalyzed by low-valent nickel complexes
Author/Authors
Lipshutz، نويسنده , , Bruce H. and Tomioka، نويسنده , , Takashi and Pfeiffer، نويسنده , , Steven S.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
7737
To page
7740
Abstract
Treatment of aryl chlorides with catalytic amounts of (PPh3)2NiCl2+PPh3 in the presence of an equivalent of Me2NH·BH3 and either K2CO3 or Cs2CO3 in CH3CN under mild conditions leads to the corresponding product of reduction. Aryl bromides and iodides can also be reduced, selectively, using this reagent combination.
Keywords
Dehalogenation , Nickel catalyst , aryl halides , amine-boranes
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1647932
Link To Document