Trifluoromethylation of heterocumulenes with trimethyl(trifluoromethyl)silane in the presence of fluoride ions: synthesis of trifluoroacetamides and trifluorothioacetamides from isocyanates and isothiocyanates
Author/Authors :
Kirij، نويسنده , , Nataliya V and Yagupolskii، نويسنده , , Yurii L and Petukh، نويسنده , , Nataliya V. and Tyrra، نويسنده , , Wieland and Naumann، نويسنده , , Dieter، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
3
From page :
8181
To page :
8183
Abstract :
Trimethyl(trifluoromethyl)silane reacts in the presence of fluoride ions with isocyanates and isothiocyanates under mild conditions to give corresponding trifluoroacetamides and trifluorothioacetamides in high yields.