Title of article
Photoinduced functionalization of the C-20 methyl group of the nor-diterpene atractyligenin
Author/Authors
Buscemi، نويسنده , , Silvestre and Rosselli، نويسنده , , Sergio and Bruno، نويسنده , , Maurizio and Vivona، نويسنده , , Nicolٍ and Piozzi، نويسنده , , Franco، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
3
From page
8289
To page
8291
Abstract
Irradiation of the nor-diterpene atractyligenin at λ=254 nm in methanol gave, on one hand, the decarboxylation product, and provided, on the other hand, the transformation of the C-20 angular methyl into a methylene-carbomethoxy group. A photochemical pathway involving formation of C-19/C-20 bond is suggested.
Keywords
Atractyligenin , photochemistry , photofunctionalization of C-20 methyl
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1648183
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