Title of article :
Control on enantioselectivity with pressure for lipase-catalyzed esterification in supercritical carbon dioxide
Author/Authors :
Matsuda، نويسنده , , Tomoko and Kanamaru، نويسنده , , Ryuzo and Watanabe، نويسنده , , Kazunori and Harada، نويسنده , , Tadao and Nakamura، نويسنده , , Kaoru، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
The enantioselectivity of lipase-catalyzed esterification of 1-(p-chlorophenyl)-2,2,2-trifluoroethanol in supercritical carbon dioxide changed continuously from E=10 to 50 by decreasing the pressure at 55°C. The effect of the solvent on enantioselectivity was examined without changing the kind of solvent.
Keywords :
Supercritical carbon dioxide , Esterification , Trifluoromethyl alcohol , Lipase , Enantioselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
