The bicyclo[2.1.1]hexan-2-one system: a new probe for the experimental and computational study of electronic effects in π-facial selectivity in nucleophilic additions
Author/Authors :
Mehta، نويسنده , , Goverdhan and Singh، نويسنده , , S.Robindro and Gagliardini، نويسنده , , Vanessa and Priyakumar، نويسنده , , U.Deva and Sastry، نويسنده , , G.Narahari، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
4
From page :
8527
To page :
8530
Abstract :
The remotely substituted 5-exo-bicyclo[2.1.1]hexan-2-one system is introduced as a new probe to study long range electronic effects on π-face selectivity during hydride reduction and a systematic computational study demonstrates good predictability at the semi-empirical level.
