Acceleration of ruthenium(II)- and rhodium(I)-catalyzed hydrogen-transfer reaction by rare earth metal triflates
Author/Authors :
Matsunaga، نويسنده , , Hirofumi and Yoshioka، نويسنده , , Naoko and Kunieda، نويسنده , , Takehisa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Pages :
3
From page :
8857
To page :
8859
Abstract :
The addition of Yb(OTf)3 as an additive considerably accelerates the RuCl2(PPh3)3- and RhCl(PPh3)3-catalyzed hydrogen-transfer reduction of both aromatic and aliphatic ketones in which Ru:Yb ratios of 1:2–1:4 are critically important for achieving acceleration.
