Title of article
Homoallylic alcohols and trichloroacetamides as hydrogen bond donors for directed dihydroxylation
Author/Authors
Donohoe، نويسنده , , Timothy J and Mitchell، نويسنده , , Lee and Waring، نويسنده , , Michael J and Helliwell، نويسنده , , Madeleine and Bell، نويسنده , , Andrew and Newcombe، نويسنده , , Nicholas J، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2001
Pages
4
From page
8951
To page
8954
Abstract
The synthesis and directed dihydroxylation of a series of homoallylic alcohols and trichloroacetamides is described. Using the combination of OsO4 and TMEDA, moderate to high levels of stereoselectivity were obtained, depending upon the structure of the substrate. Proof of the structure of two osmate esters was obtained through X-ray crystallography.
Journal title
Tetrahedron Letters
Serial Year
2001
Journal title
Tetrahedron Letters
Record number
1648716
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