Author/Authors :
Rele، نويسنده , , Shyam and Chattopadhyay، نويسنده , , Subrata and Nayak، نويسنده , , Sandip K، نويسنده ,
Abstract :
External addition of inorganic salts (Group I and II metal halides) to the preformed low-valent titanium reagent A (TiCl3–Li–THF) dramatically enhanced its activity. The new reagents were used to carry out various SET reactions including McMurryʹs olefination at a faster rate even at ambient temperature.