Title of article :
Homo-Brook route to benzazocenols and congeners via allylsilane-derived aziridines
Author/Authors :
Ducray، نويسنده , , Richard and Cramer، نويسنده , , Nicolai and Ciufolini، نويسنده , , Marco A، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2001
Abstract :
We describe a concise entry to benzazocenols intermediates for mitomycinoids via a homo-Brook rearrangement–ring opening sequence of a silylated aziridine. The latter is obtained by intramolecular 1,3-dipolar cycloaddition of an azide with an allylsilane, followed by irradiation of the resulting triazoline.
Keywords :
allylsilanes , antitumor agents , Azides , Aziridines , Heterocycles , mitomycinoids
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
