Author/Authors :
Fujimura، نويسنده , , Takashi and Nakashima، نويسنده , , Hiromi and Sakagami، نويسنده , , Hideki and Taniguchi، نويسنده , , Takahiko and Ogasawara، نويسنده , , Kunio، نويسنده ,
Abstract :
A diastereoselective route to an enantiopure 4,4-disubstituted cyclohex-2-en-1-ol has been developed using the synthetic equivalent of chiral 4-hydroxycyclohex-2-en-1-one. Its stereochemistry has been determined by its transformation into the Aspidosperma indole alkaloid (+)-quebrachamine.
