Title of article
Facile preparation and rearrangement of allylic dialkoxy disulfides
Author/Authors
Braverman، نويسنده , , Samuel and Pechenick، نويسنده , , Tatiana، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
499
To page
502
Abstract
Allylic dialkoxy disulfides were obtained in good yields and their reactivity has been investigated. Similarly to allylic sulfoxylates, these esters undergo double [2,3]-sigmatropic rearrangement to the appropriate vic-disulfoxides. The latter, being unstable, undergoes spontaneous rearrangement to the corresponding thiosulfonates.
Keywords
allylic dialkoxy disulfides , thiosulfonates , vic-disulfoxides , sigmatropic rearrangement
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1649334
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