Title of article
An intramolecular Pauson–Khand approach to the synthesis of chiral cyclopentadienes
Author/Authors
Rios، نويسنده , , Ramon and Moyano، نويسنده , , Albert and Pericàs، نويسنده , , Miquel A، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
1023
To page
1026
Abstract
A procedure for the synthesis of chirally-substituted cyclopentadienes has been developed by employing the intramolecular Pauson–Khand reaction of chiral amides derived from 8-nonen-2-ynoic acid. Hydride-mediated reduction of the resulting cyclopentenone adducts followed by acid-catalysed dehydration leads to the formation of the corresponding cyclopentadienes in good overall yield.
Keywords
cyclopentadienes , cyclopentenones , Pauson–Khand reactions
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1649731
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