Title of article
Reexamination of orbital interactions in Diels–Alder reactions
Author/Authors
Ogawa، نويسنده , , Atsushi and Fujimoto، نويسنده , , Hiroshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
2055
To page
2057
Abstract
An application of the perturbation theory to the [4+2] addition of butadiene has demonstrated that the effect of secondary orbital interactions should be much less significant than has been assumed within the frontier orbital scheme. This has been confirmed by a numerical analysis with respect to the endo transition state of the Diels–Alder reaction between butadiene and maleic anhydride.
Keywords
Theoretical calculations , Diels–Alder reaction , secondary orbital interactions
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1650521
Link To Document