• Title of article

    Platinum complex-catalyzed hydrosilylation of 2,2-diaryl-1-methylenecyclopropane affording (silylmethyl)cyclopropane

  • Author/Authors

    Nishihara، نويسنده , , Yasushi and Itazaki، نويسنده , , Masumi and Osakada، نويسنده , , Kohtaro، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    3
  • From page
    2059
  • To page
    2061
  • Abstract
    PtI2(PPh3)2-catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of SiH bond converts 2,2-diaryl-1-methylenecyclopropane into its silylated derivative without ring-opening.
  • Keywords
    Cyclopropanes , silicon and compounds , Thorpe–Ingold effect , addition reactions , Platinum
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1650524

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1650524