Title of article :
Generation and regioselective reactions of α,α-bis(silyl)-substituted allylcopper reagents—synthesis of 1,1-disilylalkenes
Author/Authors :
Kondo، نويسنده , , Junichi and Inoue، نويسنده , , Atsushi and Shinokubo، نويسنده , , Hiroshi and Oshima، نويسنده , , Koichiro، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Treatment of chlorobis(methyldiphenylsilyl)methyllithium with vinylic Grignard reagents and CuCN·2LiCl afforded α,α-bis(silyl)-substituted allylic copper species. The reactions of the reagents with electrophiles provided a variety of 1,1-disilylalkenes.
Keywords :
allylation , carbenoids , Copper , Grignard reagents , 1 , 1-disilylalkenes
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
