Title of article
Homogeneous cis-dihydroxylation and epoxidation of olefins with high H2O2 efficiency by mixed manganese/activated carbonyl catalyst system
Author/Authors
Brinksma، نويسنده , , Jelle and Schmieder، نويسنده , , Lizette and van Vliet، نويسنده , , Gerbert and Boaron، نويسنده , , Rob and Hage، نويسنده , , Ronald and De Vos، نويسنده , , Dirk E and Alsters، نويسنده , , Paul L and Feringa، نويسنده , , Ben L، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
2619
To page
2622
Abstract
The use of [Mn2O3(tmtacn)2](PF6)2 (tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane) in combination with glyoxylic acid methylester methyl hemiacetal (GMHA) results in a highly active and hydrogen peroxide efficient catalyst for the epoxidation of olefins as well as the first homogeneous catalytic cis-dihydroxylation system with H2O2 and with turnover numbers up to 420.
Keywords
Hydrogen peroxide , cis-diols , epoxides , Oxidation , Manganese
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1650919
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