Title of article
Highly diastereoselective TiCl4 mediated addition of (E)-cinnamyl(tributyl)tin to α-keto esters
Author/Authors
Basavaiah، نويسنده , , Deevi and Sreenivasulu، نويسنده , , Bandaru، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
2987
To page
2990
Abstract
Highly syn-(87–98%) diastereoselective addition of (E)-cinnamyl(tributyl)tin to α-keto esters under the influence of titanium tetrachloride, leading to the isolation of pure alkyl syn-2-aryl-2-hydroxy-3-phenylpent-4-enoates in 50–80% yields, is described.
Keywords
allylation , Titanium tetrachloride , ?-keto esters , cinnamyl(tributyl)tin , diastereoselectivity
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1651191
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