Title of article :
Stereoselective synthesis of 4a-fluoro-5,10-ethenobenzo[f]quinazolines via photo-Diels–Alder reaction of 5-fluoro-1,3-dimethyluracil with naphthalenes
Author/Authors :
Ohkura، نويسنده , , Kazue and Sugaoi، نويسنده , , Tatsuyuki and Nishijima، نويسنده , , Ken-ichi and Kuge، نويسنده , , Yuji and Seki، نويسنده , , Koh-ichi، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
UV-irradiation of a solution of 5-fluoro-1,3-dimethyluracil (5-FDMU) in aprotic media effected a stereoselective 1,4-cycloaddition reaction to give a barrelene derivative in high yield. In direct contrast, irradiation of a solution of 5-FDMU and naphthalene in a protic medium afforded 5-(1-naphthyl)uracil as the major product.
Keywords :
1 , 5-fluoro-1 , 4-cycloaddition , 3-dimethyluracil , naphthalene , Photocycloaddition , Photoreaction
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters