Title of article :
Dispiro[cyclohexane-1,1′-(1′,7′-dihydrocyclopenta[f]azulenium)-7′,1′′-cyclohexane] perchlorate, a new highly stable hydrocarbon cation
Author/Authors :
Oda، نويسنده , , Mitsunori and Kainuma، نويسنده , , Hitoshi and Miyatake، نويسنده , , Ryuta and Kuroda، نويسنده , , Shigeyasu، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
The title cation was synthesized from 1,6-diacetylcyclohepta-1,3,5-triene by a six-step sequence involving an aldol reaction, the Nazarov cyclization, the Shapiro reaction and hydride abstraction, and its pKR+ value was found to be 13.2, providing a new access to highly stable hydrocarbon cations.
Keywords :
X-ray crystal structures , azulenes , cyclohexanes , spiro compounds , carbenium ions
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
