Title of article :
Cyclopropyl phosphonate ester synthesis catalyzed by ruthenium porphyrins: first characterization of a phosphonate carbene complex
Author/Authors :
Simonneaux، نويسنده , , Gérard and De Montigny، نويسنده , , Frédéric and Paul-Roth، نويسنده , , Christine and Gulea، نويسنده , , Mihaela and Masson، نويسنده , , Serge، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Pages :
3
From page :
3685
To page :
3687
Abstract :
Catalytic systems derived from Ru(CO)porphyrins are extremely efficient at converting styrene and diisopropyl diazomethyl phosphonate to cyclopropyl phosphonate esters in high yields and with high stereoselectivity; a monocarbene complex Ru(TPP)(CH{P(O)(OiPr)2}) has been isolated as a possible catalytically active species.
Keywords :
Catalysts , Ruthenium complex , Cyclopropanation
Journal title :
Tetrahedron Letters
Serial Year :
2002
Journal title :
Tetrahedron Letters
Record number :
1651691
Link To Document :
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