Author/Authors :
Shchepina، نويسنده , , N.E and Badun، نويسنده , , G.A and Nefedov، نويسنده , , V.D and Toropova، نويسنده , , M.A and Fedoseev، نويسنده , , V.M and Avrorin، نويسنده , , V.V and Lewis، نويسنده , , Scott B، نويسنده ,
Abstract :
The nuclear–chemical method has been used for the synthesis of previously unknown multivalent fluorine derivatives, namely (4-methylphenyl)phenylfluoronium. The synthesis includes the ion-molecular reaction of free phenyl cations generated by tritium β-decay with 4-methylhalobenzenes. The influence of the halogen atom (F, Cl, Br, I) as well as effects of the methyl substituent on the yields of the corresponding halonium compounds have been investigated.
Keywords :
halogen compounds , Radiation chemistry , Labeling , phenyl cations
