Title of article
Indium-mediated atom-transfer cyclizations and reductive cyclizations
Author/Authors
Yanada، نويسنده , , Reiko and Nishimori، نويسنده , , Nobuaki and Matsumura، نويسنده , , Akira and Fujii، نويسنده , , Nobutaka and Takemoto، نويسنده , , Yoshiji، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
4585
To page
4588
Abstract
Novel indium-mediated reactions have been studied. Treatment of iodoalkyne with In (0.5 equiv.) and I2 (0.5 equiv.) in MeOH promotes the atom-transfer 5-exo-cyclization. In contrast, the reaction with In (2 equiv.) and I2 (1 equiv.) gives rise to a reductive 5-exo-cyclized product.
Keywords
Indium , radical , iodine , atom-transfer cyclization , reductive cyclization
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652318
Link To Document