Title of article :
Chemo- and regioselective oxidation of adamantyl derivatives by dioxiranes
Author/Authors :
DʹAccolti، نويسنده , , Lucia and Kang، نويسنده , , Jiang-ping and Khan، نويسنده , , Saeed and Curci، نويسنده , , Ruggero and Foote، نويسنده , , Christopher S.، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2002
Abstract :
Methyl(trifluoromethyl) dioxirane (1) gives direct chemo- and regioselective oxidation of methyleneadamantane oxide (2) and isopropylideneadamantane oxide (3) in high yield under mild conditions. Secondary CH are not appreciably oxidized and high regioselectivities were observed for attack at tertiary CH.
Keywords :
Dioxiranes , epoxides , Oxidation , Insertion , Chemoselectivity , regioselectivity
Journal title :
Tetrahedron Letters
Journal title :
Tetrahedron Letters
