Title of article
Six- versus five-membered ring formation in radical cyclization of 1-vinyl-5-methyl-5-hexenyl radicals
Author/Authors
G?mez، نويسنده , , Ana M. and Company، نويسنده , , Mar??a D. and Uriel، نويسنده , , Clara and Valverde، نويسنده , , Seraf??n and L?pez، نويسنده , , J.Crist?bal، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
4997
To page
5000
Abstract
Radical cyclization of 1-vinyl-5-methyl-5-hexenyl radicals (radical numbering) affords six-membered ring products prevailing over the isomeric five-membered ring compounds; the former are generated through two reaction pathways: 6-endo–trig ring closure and rearrangement of intermediate methylenecyclopentyl radicals obtained by 5-exo–trig cyclization.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652607
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