• Title of article

    Comparative investigation of kinetic consequences associated with long-range electronic effects on catalytic ruthenium-promoted ring-closing metathesis

  • Author/Authors

    Basu، نويسنده , , Kallol and Cabral، نويسنده , , Jose A and Paquette، نويسنده , , Leo A، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    5453
  • To page
    5456
  • Abstract
    When exposed to the Grubbs ruthenium catalyst, trienyl substrates of type 4 undergo highly regioselective ring closure to give the common product 5. These reactions proceed invariably under pseudo-first-order kinetics, considerably faster when X=H (t1/2=9.1), followed by X=CO2Et (t1/2=26.5).
  • Keywords
    metathesis , Kinetics , Ruthenium , Electronic effects , cyclization
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1652921

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1652921