Title of article
Indium-mediated allylation reaction of difluoroacetyltrialkylsilanes in aqueous media
Author/Authors
Chung، نويسنده , , Woo Jin and Higashiya، نويسنده , , Seiichiro and Welch، نويسنده , , John T، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
5801
To page
5803
Abstract
Indium-mediated allylations of difluoroacetyltrialkylsilanes in aqueous media give homoallylic alcohols exclusively. The common Brook rearrangement C- to O-silyl group migration is totally suppressed with no detectable formation of enol silyl ethers. The influence of water on the allylation reaction is also described.
Keywords
allylation , Homoallylic alcohol , Enol silyl ether , Indium , Brook rearrangement , difluoroacetyltrialkylsilane
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1653147
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