Title of article
New synthesis of α-benzylaldehydes from 2-(dimethylphenylsilylmethylene)alkanals by fluoride promoted phenyl migration
Author/Authors
Aronica، نويسنده , , Laura Antonella and Morini، نويسنده , , Francesca and Caporusso، نويسنده , , Anna Maria and Salvadori، نويسنده , , Piero، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
5813
To page
5815
Abstract
α-Benzyl aldehydes are prepared from easily available β-silylalkenals and fluoride reagents, under mild experimental conditions; the reaction occurs instantaneously with almost quantitative yields. A plausible mechanism is suggested, which involves a 1,2-phenyl migration from the silicon to the adjacent carbon atom.
Keywords
?-benzyl aldehydes , ?-silylalkenal , Alkynes , silicon and compounds
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1653155
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